Laboratoire de Physique de la Matière Condensée

Groupe Electrochimie et Couches Minces

Contact : catherine.henry-de-villeneuve-AT-polytechnique.edu

+33 (0)1 69 33 46 64

Activités de Recherche
– Fonctionnalisation de surface/Chimie de surface
– Monocouches organiques sur Silicium
– Organisation/Interactions moléculaires sur les surfaces
– Monocouches photo-commutables sur Silicium
– Croissance et propriétés de couches minces métallorganiques :
    • Metal Organic Framework (MOF) : en savoir plus
    • Analogues du Bleu de Prusse (PBA)
– Surfaces Fonctionnelles pour la bio/chem détection
– Anodes à base de Silicium amorphe (aSi) pour des batteries Li ions : en savoir plus

Domaines de compétences
Scientifiques : Nanosciences, Chimie de surface, Electrochimie, Croissance
Expérimentales : Caractérisation de surfaces, Microscopies en champs proche (AFM, STM), Spectroscopie FTIR, Diffraction de rayons X.

Expériences professionnelles antérieures
1993-2003    Chargée de recherche – Laboratoire des Interfaces et Systèmes Electrochimiques (LISE) - UPR15 CNRS – UPMC Paris.
1991–1993    ATER – Dpt de Pysico-Chimie des Matériaux - Ecole Centrale de Lyon

Formation
1992    Doctorat de L’Université Claude Bernard (UCB) – Lyon I
    Dpt de Physico-Chimie des Matériaux – Ecole Centrale de Lyon.

Publications récentes
• Growth of Fe-BDC Metal Organic Frameworks onto functionalized Si (111) surfaces, H. Yuan, W. Fu, N. Soulmi, C. Serre, N. Steunou, M. Rosso, C. Henry-de-Villeneuve, Chemistry - An Asian Journal 17 (2022) e202200129.
https://doi.org/10.1002/asia.202200129
• Affinity driven ion exchange EG-OFET sensor for high selectivity and low limit of detection of Cesium in seawater, T.P. Nuy, V. Kilinc, R. Hayakawa, C. Henry-de-Villeneuve, J.-M. Raimundo, Y. Wakayama, A. Charrier, Sensors & Actuators B : Chemical 351 (2022) 130956.
https://doi.org/10.1016/j.snb.2021.130956
• Controlling homogeneity of the first lithiation in methylated amorphous silicon, Y. Feng, A. Cheriet, M. Panagopoulou, C. Henry-de-Villeneuve, M. Rosso, F. Ozanam, Electrochimica Acta 403 (2022) 139655.
https://doi.org/10.1002/asia.202200129
• ToF-SIMS Li depth profiling of pure and methylated amorphous silicon electrodes after their partial lithiation, Y. Feng, B. M. Koo, A. Seyeux, J. Światowska, C. Henry de Villeneuve, M. Rosso, F. Ozanam, ACS Appl. Mater. Interfaces 14 (2022) 35716-35725.
https://doi.org/10.1021/acsami.2c08203
• Influence of Light Polarization on Photoswitching of Fulgimide Monolayers on Surfaces, S. Klaes, C. Henry-de-Villeneuve, F. Ozanam, C. Barta, K. Rueck-Braun, R. Métivier, P. Allongue, J. Phys. Chem. C (2019) 123, 19, 12223-12233.
https://doi.org/10.1021/acs.jpcc.9b00836S
• Lithiation of pure and methylated amorphous silicon : Monitoring by operando optical microscopy and ex situ atomic force microscopy, Y. Feng, T.-D.-T. Ngo, M. Panagopoulou, A. Cheriet, B.-M. Koo, C. Henry-de-Villeneuve, M. Rosso, F. Ozanam, Electrochimica Acta 302 (2019) 249-258.
https://doi.org/10.1016/j.electacta.2019.02.016
• Structure of Mixed Acid/Decyl Monolayers Grafted on Oxide-Free Si(111) Surfaces, C. Henry-de-Villeneuve, T.-L. Nguyen-Le, F. Ozanam, P. Allongue, Langmuir (2019) 35, 7, 2547-2553.
https://pubs.acs.org/doi/10.1021/acs.langmuir.8b03746
• Novel and innovative interface as potential active layer in Chem-FET sensor devices for the specific sensing of Cs2+, V. Kilinc, C. Henry-de-Villeneuve, T. P. Nguy, Y. Wakayama, A. Charrier, J.-M. Raimundo, ACS Applied Materials & Interfaces (2019).
https://doi.org/10.1021/acsami.9b18188
• Active Acetylcholinesterase Immobilization on a Functionalized Silicon Surface, K. Khaldi, S. Sam, A. C. Gouget-Laemmel, C. Henry de Villeneuve, A. Moraillon, F. Ozanam, J. Yang, A. Kermad, N. Ghellai, N. Gabouze, Langmuir (2015) 31, 8421-8428.
http://pubs.acs.org/doi/abs/10.1021/acs.langmuir.5b01928
• Poly(dimethylsiloxane) as a pre-coating in layer-by-layer films containing phosphotungstate nanoclusters electrochemically sensitive toward s-triazines, A. L. Souza, G. Tremiliosi-Filho, L. T. Kubota, R. K. Mendes, A. M. B. do Rego, O. N. Oliveira, C. Henry de Villeneuve, J. N. Chazalviel, P. Allongue, F. Ozanam, and U. P. Rodrigues, Rsc. Advances (2014) 4, 29612.
http://dx.doi.org/10.1039/c4ra01468e
• Methylated silicon : A longer cycle-life material for Li-ion batteries,
L. Touahir, A. Cheriet, D. Alves Dalla Corte, J.-N. Chazalviel, C. Henry de Villeneuve, F. Ozanam, I. Solomon, A. Keffous, N. Gabouze, M. Rosso, J. Power Sources (2013) 240, 551-557.
https://doi.org/10.1016/j.jpowsour.2013.04.089
• Thermal decomposition of alkoxy monolayers on silicon : a mechanistic model, D. Dusciac, C. Henry de Villeneuve, P. Allongue, F. Ozanam, J.-N. Chazalviel, Surface Science (2013) 609, 230-235.
https://doi.org/10.1016/j.susc.2012.12.008
• Quantitative IR Readout of Fulgimide Monolayer Switching on Si(111) Surfaces, C. Henry de Villeneuve, F. Michalik, J.-N. Chazalviel, K. Rück-Braun, P. Allongue, Adv. Mater. (2013) 25, 416-421.
https://doi.org/10.1002/adma.201201546